Product ID:GENERTRON AZ-50 (R-507)
MSDS Date:08/01/1995
FSC:6830
NIIN:00N076833
MSDS Number: CDWXB

ALLIED SIGNAL INC

101 COLUMBIA ROAD
MORRISTOWN, NJ 07962
US

Emergency Phone: 201-455-2000

Info Phone: 201-455-4157

Cage: 0LYW2

HONEYWELL INTL INC ENVIRONMENTAL SYSTEMS AND SERVICES

MORRISTOWN, NJ 07962 US

Telephone: 973-455-3922

Cage: 70308

ETHANE, PENTAFLUORO-; (PENTAFLUOROETHANE)

CAS: 354-33-6

RTECS: KI6365000

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRIFLUORO-; (1,1,1-TRIFLUOROETHANE)

CAS: 420-46-2

RTECS: KJ4110000

OSHA PEL N/K

ACGIH TLV: N/K

SODIUM, POTASSIUM, CALCIUM, POWDERED

RTECS: 9999999ZZ

OXYGEN LEVELS IN AIR ARE REDUCED TO 12-14%

RTECS: 9999999ZZ

INCRD PULSE RATE & DEEPER RESP WILL OCCUR. AT HIGH

RTECS: 9999999ZZ

IS UNLIKELY, DISCOMFORT IN THE GI TRACT WOULD RSLT

RTECS: 9999999ZZ

EVOLUTION OF GAS. IN ADDITION, SOME OF THE EFFECTS OF

RTECS: 9999999ZZ

IMMED REMOVE TO FRESH AIR. IF

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REQ, PROVIDED A QUALIFIED OPERATOR IS AVAIL. CALL A

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INGEST IS UNLIKELY BECAUSE OF THE PHYSICIAL

RTECS: 9999999ZZ

NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO SO BY A

RTECS: 9999999ZZ

SUSPECTED, DO NOT GIVE EPINEPHRINE. TREAT

RTECS: 9999999ZZ

LOW LYING AREAS. SPILLS & RELEASE MAY HAVE TO BE

RTECS: 9999999ZZ

SEE THE REGULATORY INFORMATION SECTION (#15)

RTECS: 9999999ZZ

DISP BY LICENSED WASTE DISP COMPANY MAY BE

RTECS: 9999999ZZ

SHIPPED. USE &/ALTERATIONS TO THE PROD SUCH AS

RTECS: 9999999ZZ

OF THE MATERIAL AND ALTER THE RCRA CLASSIFICATION

RTECS: 9999999ZZ

DMG. DO NOT HEAT THE CNTNR/STORE AT A TEMP ABOVE

RTECS: 9999999ZZ

BE AVOIDED. CLOSE VALVE TIGHTLY AFTER USED & WHEN

RTECS: 9999999ZZ

FOR AREAS OF PRINCIPAL EXPOSURE. FOR TANK CLEANING

RTECS: 9999999ZZ

OPERATING AND STORAGE AREAS.

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

OUTER LAYER & COATED DURAFAB (2ND CHOICES

RTECS: 9999999ZZ

CONTAMINATED AND WASHED BEFORE RESUE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMER OVERVIEW: COLORLESS, VOLATILE LIQ
W/ETHERAL & FAINT SWEETISH ODOR. NON-FLAMM MATL. OVEREXP MAY CAUSE
DIZZ & LOSS OF CONC. AT HIGHER LEVELS, CNS DEPRESS & CARDIAC ARRHY
MAY RSLT FROM EXPOS. VAPS D ISPLACE AIR & CAN CAUSE ASPHY IN
CONFINED SPACES. AT HIGH TEMPS, (>250C), DECOMP PRODS MAY INCLUDE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:HYDROFLUORIC ACID (HF) & CARBONYL
HALIDES SUCH AS PHOSGENE. SKIN:IRRIT WOULD RSLT FROM A DEFAT ACTION
ON TISS. LIQ MAY CAUSE FROSTBITE. NECROSIS FROM FREEZING OF TISS
COULD OCCUR. EYES:LIQ CN TCT CAN CAUSE IRRIT, WHICH MAY BE SEV.
MIST MAY IRRIT. INHAL:AZ-50 IS LOW ODOR ACUTE TOX IN ANIMALS. WHEN
(ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:PROMPTLY FLUSH W/H*2O UNTIL ALL CHEM IS REMOVED. IF
THERE IS EVIDENCE OF FROSTBITE, BATHE (DO NOT RUB) W/LUKEWARM, NOT
HOT, H*2O. IN THE ABSENCE OF H*2O, COVER W/SOFT CLEAN CLOTH/SIMILAR
COVERING . CALL MD. EYE:IMMED FLUSH W/LRG AMTS, OF H*2O FOR AT
LEAST 15 MIN. [IN CASE OF FROSTBITE, H*2O SHOULD BE LUKEWARM - NOT
HOT], LIFTING EYELIDS OCCAS TO FACILITATE IRRIT. GET MED ATTN IF
SYMPS (ING 7)

Lower Limits:NONE BY ASTM
Upper Limits:NONE BY ASTM
Extinguishing Media:USE ANY STANDARD AGENT - CHOOSE THE ONE MOST
APPROPRIATE FOR TYPE OF SURROUNDING FIRE (MATL ITSELF IS NOT
FLAMMABLE).
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . PROPER EYE & SKIN PROT SHOULD ALSO BE PROVIDED. USE
WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:THIS MATL MAY BE FLAMM WHEN MIXED W/AIR
UNDER PRESS & EXPOSED TO STRONG INGITION SOURCES. CNTCT W/CERTAIN
REACTIVE METALS MAY RSLT IN FORMATION OF (SUPDAT)

Spill Release Procedures:(ALWAYS WEAR REC PERS PROT EQUIP.) EVACUATE
ALL UNPROTECTED PERS. PROT PERS SHOULD REMOVE ANY IGNIT SOURCES &
SHUT OFF LEAK IF W/OUT RISK, & PROVIDE VENT. UNPROTECTED PERS
SHOULD NOT RETURN UNTIL AIR HAS BEEN TESTED & DETERMINED SAFE,
INCL(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:(ALWAYS WEAR REC PERS PROT EQUIP.)
AVOID BRTHG VAPS/LIQ CONT W/EYES, SKIN/CLTHG. DO NOT PUNCTURE/DROP
CYL/EXPOS THEM TO OPEN FLAME/EXCESSIVE HEAT.
Other Precautions:USE AUTHORIZED CYLINDERS ONLY. FOLLOW STANDARD SAFETY
PRECS FOR HNDLG & USE OF CYLINDERS OF COMPRESSED GAS. STORE IN A
COOL, WELL-VENT AREA OF LOW FIRE RISK & OUT OF DIRECT SUNLIGHT.
PROTECT CYLINDER & ITS FITTINGS FROM PHYSICAL (ING 18)

Respiratory Protection:NONE GENERALLY REQ FOR ADEQUATELY VENT WORK
SITUATIONS. FOR ACCIDENTAL RELEASE, NON-VENT SITUATIONS/RELS IN
CONFINED SPACE, USE A NIOSH APPRVD SCBA/SUPPLIED AIR RESP. FOR
ESCAPE USE THE FORMER/NIOSH-A PPRVD GAS MASK W/ORGANIC VAP
CANISTER.
Ventilation:PROVIDE LOC EXHST AT FILLING ZONES & AREAS WHERE LEAKAGE IS
PROBABLE. MECH (GEN) VENT MAY BE ADEQ FOR OTHER (ING 21)
Protective Gloves:IMPERVIOUS GLOVES W/MYLAR (ING 23)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 22)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . IMPERIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE & WASH CLOTHING PROMPTLY, IF WET. ANY
NON-IMPERVIOUS CLOTHING SHOULD ALSO BE PROMPTLY REMOVED WHEN (ING
24)
Supplemental Safety and Health
SPEC GRAV:1.07 @ 21.1C (70F) (H*2O=1). VP:153.9 PSIG @ 70F, 366.8 PSIG
@ 130F. PH:NEUTRAL % VOL:68F(20C) 100 EXPLO HAZ: EXPLO/EXOTHERMIC
RXNS UNDER SPECIFIC CNDTNS (E.G., VERY HIGH TEMP &/APPROP PRESS ).
CNDTNS (STAB):WELDING MAY YIELD TOX/CORR DECOMP PRODS. MATLS TO
AVOID:EXOTHERMIC RXN). CHEMICALLY ACTIVE (ING 3)

Boiling Pt:B.P. Text:-52F,-47C
Vapor Pres:SUPDAT
Vapor Density:3.43
Spec Gravity:SUPDAT
pH:SUPDAT
Evaporation Rate & Reference:>1 COMPARED TO: CC1*4
Appearance and Odor:CLEAR COLORLESS LIQUID OR VAPOR. FAINT ETHERAL
ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
(UNDER SPECIFIC CNDTNS: E.G., VERY HIGH TEMP &/APPROP PRESS). FRESHLY
ABRADED ALUMINUM SURFS (MAY CAUSE STRONG (SUPDAT)
Stability Condition to Avoid:DO NOT MIX W/OXYGEN/AIR ABOVE ATM PRESS.
ANY SOURCE OF HIGH TEMP, SUCH AS LIGHTED CIGARETTES, FLAMES, HOT
SPOTS,(SUPDAT)
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, AND POSSIBLE
CARBONYL HALIDES. THESE ARE TOXIC AND CORROSIVE.

Waste Disposal Methods:(DISPOSAL MUST COMPLY W/FED, STATE, & LOCAL
DISP/DISCHARGE LAWS). DISP OF AZ-50 AZEOTROPE MAY BE SUBJECT TO FED
REGS. USERS SHOULD REVIEW THEIR OPERATIONS, THEN CONSULT W/APPROP
REGULATORY AGENCIES BE FORE DISCHARGING/DISPOSING OF WASTE MATL.
(ING 15)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.